A combinatory ferroelectric compound bridging simple ABO3 and A-site-ordered quadruple perovskite
نویسندگان
چکیده
Abstract The simple ABO 3 and A-site-ordered AA? B 4 O 12 perovskites represent two types of classical perovskite functional materials. There are well-known with ferroelectric properties, while there is still no report ferroelectricity due to symmetry breaking transition in quadruple perovskites. Here we the high pressure synthesis an PbHg Ti , only known that transforms from high-temperature centrosymmetric paraelectric phase low-temperature non-centrosymmetric phase. coordination chemistry Hg 2+ changed square planar as typical a rare stereo type 8 ligands . Thus appears be combinatory link perovskites, sharing both displacive former structure latter. This example so far showing -type opens direction search for
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ژورنال
عنوان ژورنال: Nature Communications
سال: 2021
ISSN: ['2041-1723']
DOI: https://doi.org/10.1038/s41467-020-20833-6